My Wife and I were watching some concert video of The White Stripes and at some point they did their cover of I Just Don't Know What To Do With Myself. I noted that it was a cover but didn't remember who made it famous. I thought it was a show tune but in retrospect, I must have been thinking of a great scene from My Best Friend's Wedding.

Julia Roberts plays the friend of a guy who is getting married and since she wants the guy, she spends much of the movie trying to make his fiancee look bad. In this scene, knowing that the girl, played by Cameron Diaz is shy and cannot sing, puts her on the spot at a karaoke bar. The girl tries so hard and is so earnest that she wins over the whole bar and the guy loves her even more. Major backfire!

A little research showed that it goes much further back than this movie.

DUSTY SPRINGFIELD-I JUST DON'T KNOW (WHAT TO DO WITH MYSELF)
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Oh yeah, here is most famous (now) version...